Search results for "Surface chemical"
showing 5 items of 5 documents
The role of surface chemical states on the photocatalytic behavior of all-inorganic mixed halide perovskite nanocrystals
2019
Diacetylene Linked Anthracene Oligomers Synthesized by One-Shot Homocoupling of Trimethylsilyl on Cu(111)
2018
On-surface chemical reaction has become a very powerful technique to conjugate small precursor molecules and several reactions have been proposed with the aim to fabricate functional nanostructures on surfaces. Here we present an unforeseen adsorption mode of 9,10-bis-((trimethylsilyl)ethynyl)anthracene on a Cu(111)surface and the resulting one-shot desilylative homocoupling of of the adsorbate by annealing at 400 K. With a combination of high-resolution atomic force microscopy and density functional theory calculations, we found that the triple bonds and silicon atoms of the monomer chemically interact with the copper surface. After the oligomerization, we discovered that the anthracene un…
Qualitative investigations of boundary value problem for self‐similar second order system which arises from modeling of surface chemical reactions
1997
„Qualitative investigations of boundary value problem for self‐similar second order system which arises from modeling of surface chemical reactions" Mathematical Modelling Analysis, 2(1), p. 41-47 First Published Online: 14 Oct 2010
Self‐similar problems for modeling the surface chemical reactions with the gravitation
1998
The mathematical model of a chemical reaction which takes place on the surface of the uniformly moving vertically imbedded glass fibre material is considered. The effect of gravitation is taken into account. Boussinesq's and boundary layer fittings allow to derive boundary value problems for self‐similar systems of ordinary differential equations. First Published Online: 14 Oct 2010
Unravelling the Photocatalytic Behavior of All-Inorganic Mixed Halide Perovskites: The Role of Surface Chemical States
2019
Within the most mesmerizing materials in the world of optoelectronics, mixed halide perovskites (MHPs) have been distinguished because of the tunability of their optoelectronic properties, balancing both the light-harvesting efficiency and the charge extraction into highly efficient solar devices. This feature has drawn the attention of analogous hot topics as photocatalysis for carrying out more efficiently the degradation of organic compounds. However, the photo-oxidation ability of perovskite depends not only on its excellent light-harvesting properties but also on the surface chemical environment provided during its synthesis. Accordingly, we studied the role of surface chemical states …